翻訳と辞書 |
Weak-Link Approach : ウィキペディア英語版 | Weak-Link Approach
The Weak-Link Approach (WLA) is a novel supramolecular coordination-based assembly methodology, first introduced in 1998 by the Mirkin Group at Northwestern University. This method takes advantage of hemilabile ligands, containing both strong and weak binding moieties, that can coordinate to metal centers and quantitatively assemble into a single condensed ‘closed’ structure (Figure 1). Unlike other supramolecular assembly methods, the WLA allows for the synthesis of supramolecular complexes that can be modulated from rigid ‘closed’ structures to flexible ‘open’ structures through reversible binding events that occur at the structural metal centers. The approach is general and has been applied to a variety of metal centers and ligand designs (Figure 2) including those with utility in catalysis and allosteric regulation. ==Classes of Allosteric Structures Assembled via the WLA==
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Weak-Link Approach」の詳細全文を読む
スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|